Nice concept and idea, however the flash coming from a different direction than the sun (in the arch and the side of the column) is very distracting to me. I do like that the subject is lit so as to not be silhouetted by the sunlight, but a more subtle touch of flash would've brought this shot to the next level.
This is a great concept, however I don't think it is a particularly flattering image of your model. Maybe if she had tilted her head back some and looked further upward? *6*
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