I tried to replicate the face from the cover of the Edgar Allan Poe story "Red Death". I used a simple laser pointer, with a black backdrop and a black hoodie.
adjusted curves
burned a little
cropped
resized
saved for web...
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Cropping out (not all) some of the blackness to the left of the face would bring more attention to the face itself. It would also disrupt the balance of 50%black, 50%with light, which tends to make the eye focus more on the art piece.