I was shooting my Veronique in the late evening sun and after the sun went down, on a way back to the car, I thought about making something like this for the Freedom challenge.
Shot with kit lens, minor adjustment of curves, cloned out a hill in the bottom.
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Great colors in the sky and fine silhouette. I might have tried this with a vertical orientation and have less emphasis on the model and more and the great expanse of the sky.
At first glimpse I thought the model was facing me and was going to complain that it needed more space on the left. Then suddenly it switched and I now see the model facing away, and the image makes a lot more sense! (And the composition is perfect.) An interesting property of some silhouettes.