I'm actually using a Canon S5 IS but as I couldn't find it on the dpc I selected the S3 (I hope that won't be a problem). Curves and levels, converted to b/w using channel mixer and sharpened it. Cleaned the skin a bit using clone brush and that's it.
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think the glasses spoil this photo, everything else about it is so natural but the glasses with there reflections draw your eyes away from the face more. omo. good luck