I used the shadow/highlight filter to bring it out of the shadows, then used the smudge and #100 airbrush to smooth the skin, Used the dodge tool to brighten areas of the face and hair. Cropped tighter and added a slight diffuse glow.
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There is something a bit strange about this one. Not sure what you did to give it the painterly look in the face. But because of her expression it works.
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