Yes! Britain indeed. Reminds me of the lady off To The Manor Born or whatever it was called! You could use the unsharp tool to tweak her facial features a bit and work on the saturation as well! In my experience I find a lot of people do like vivid colours in their wedding photos so don't be afraid to experiment.
When I saw her I immediately thought "Britain." Love the hat. I sense the focus is on it and not her face, but overall, still a pleasing image. What if you played with levels to tweak the colors?
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