This was taken in the late morning. I liked the composition but the sky didn't showcase the tree, so I did a hue change and came up with this brilliant "sunset" sky. Slight clone of power lines at the horizon, selective de-speckle of the sky due to saturation. Save for web.
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I've looked at your photo for a few minutes now. At times I get a 3-D sense. The sky seems so unnaturally orange, but with the silhouetted tree and the black border I think that's how I get that feeling. The hill line behind the tree seems a bit odd, perhaps from post-editing. Hmmm...I find this intriguing.