I remember this photo. I just couldnt rate it good due to the challenge subject matter. By the way excellent photo. Great Detail. I could look look at this all day.
Complementary colours are pairs of colours that contrast strongly when compared to each other.
Black and white are neutrals and not colours at all, and therefore they cannot be complementary colours... white shows the presence of light, and black shows the absence of light. Black and white areas next to each other do demonstrate high contrast, but high contrast gives a different visual effect than complementary colours do in a picture.
Check some of the forum discussions on complementary colours for suggestions on using colour for contrast.