LightRoom
White Balance to warm up
Increased Contrast, Highlights, shadows, black clipping and Clarity
Cropped to only the eyes.
Photoshop
Duplicate background
Added a little Turquoise to the irises
Used spot healing brush to clone out stray hairs, eyebrows, mascara
Blurred a bit on the skin and hair/eyebrows so really just the eyes pop out
Sharpened eyelashes and pupils (to make them sparkly)