i ended up doing it with layer masks, shape layers, , and guides.
basically laying the primary colors over the top of the secondary colors, and using the guides to make two overlapping rectangular selections, then invert the selection, and create another mask on the underlying layer with the inverted selction creating the mask.
not exactly what i was hoping - but i changed course anyway and didn't end up needing to do what i asked about originally.
i'd still be curious of other ways to accomplish that though.
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