When using Windows applications such as MS Word, Print Screen will take an image of the entire monitor screen, ALT + Print Screen will take only the currently active window/ dialog box.
I'm an IT Trainer so I use both a lot when creating user manuals.
I tend to PASTE mine into PaintShopPro because it's quicker for me to greyscale and then select a small area of the screen before pasting into my manual document.
I found that using Photoshop wasn't as easy because when I selected part of the image and did a copy and paste elsewhere I would always end up pasting the whole image - I had to crop and save in Photoshop before I could copy and paste into the manual.
Uugh!
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